General base-tuned unorthodox synthesis of amides and ketoesters with water.
نویسندگان
چکیده
We discovered a highly reactive λ(3)-hypervalent iodane species using an inorganic/organic base for the unorthodox synthesis of amides and ketoesters through grafting terminal alkynes. In contrast to the metal-catalyzed dehydrative approaches the in situ generated nonmetallic reagent efficiently created C-N/C-O and C[double bond, length as m-dash]O bonds with amines/alkynes and water at rt.
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ورودعنوان ژورنال:
- Chemical communications
دوره 51 2 شماره
صفحات -
تاریخ انتشار 2015